Stress corrosion cracking has been causing problems in syngas plants since they were first developed and many of these cases have been covered in previous ammonia safety conferences. This report presents findings of causes for stress corrosion cracks scc and. On 11212007 it was reported that, a nurse tank carrying anhydrous ammonia exploded. Stress corrosion cracking issues in syngas plants that may. The specificity of environments that will promote stress corrosion cracking is significant. It is important to realize that not all corrosive environments promote the formation of stress corrosion cracks. Anhydrous ammonia in carbon steels and quenchedandtempered lowalloy steels in the presence of air in addition to stress, oxygen is a critical ingredient to enable scc nitrogen aggravates the process source. Tensile residual stresses contribute to stress corrosion cracking of nurse tanks, which can cause tanks to release toxic ammonia vapor. Alberni valley multiplex ammonia leak technical safety bc.
Metallurgical evaluation of a nurse tank cracked head. At high pressure, corrosive ammonium carbamate may be formed. Stresscorrosion cracking of steel in liquefied ammonia is traced from its early recognition in the 1950s, from experiences in agricultural and industrial use from nace national association of corrosion engineers recommended dot department of transportation regulations to prevent damage, and from laboratory studies to explain the factors involved. A novel tool for inservice automated ultrasonic inspection of insulated atmospheric ammonia storage tank. Stresscorrosion cracking occurs in a susceptible material when it is exposed to sustained tensile stresses and a specific environment. Observations of corrosion product formation and stress corrosion. Stainless steels in ammonia production nickel institute.
Stress corrosion cracking is the growth of crack formation in a corrosive environment. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. Nurse tank failures most often result from stress corrosion cracking scc or. Predicted growth of throughthickness stress corrosion. Stress corrosion cracking in refrigeration systems. Significant stress corrosion cracking means a stress corrosion cracking scc cluster in which the deepest crack, in a series of interacting cracks, is greater than 10% of the wall thickness and the total interacting length of the cracks is equal to or greater than 75% of the critical length of a 50% throughwall flaw that would fail at a. Neutron diffraction analysis of residual stresses near. Stresscorrosion cracking, materials performance and. The teams primary focus has been on stress corrosion cracking scc in the steel exposed to the corrosive ammonia fig.
Houston fire department, 410 bagby street, houston, tx 77002. Oxygen levels of more than a few ppm in liquid ammonia or a few thousand ppm in gaseous ammonia can promote stress corrosion cracking in steels. The guidance is based on experience gained from inspection of ammonia tanks and the knowledge of potential failure mechanisms, which can affect the integrity of the tanks, in particular, stress corrosion cracking scc induced by ammonia under certain conditions. Problem, failure and safety analysis of ammonia plant. Several major disasters have involved stress corrosion cracking, including the rupture of highpressure gas transmission pipes, the explosion of boilers, and the destruction of power stations and oil refineries. Ammonia corrosion can cause stress corrosion cracking in steels. Stress corrosion cracking sco of carbon and alloy steels in liquid ammonia has occurred spasmodically over the last twenty years. The relationship between the concentration of copper and a the rate of dissolution and b the timetofailure for cu30zn in 15 m aqueous ammonia. Damage due to hydrogen embrittlement and stress corrosion. Stress corrosion cracking in ammonia storage iffco. Carbon steel in anhydrous ammonia can suffer from scc stress corrosion cracking. Tankers, where the tanks are to be constructed for the carriage of anhydrous ammonia at ambient temperatures.
The measures listed in these guidelines with respect to material selection, tank fabrication and inspection will be regarded as being necessary to reduce the risk of ammonia stress corrosion cracking to a minimum. The tool is designed for inspection of welds for stress corrosion. According to the american society for metals metals handbook, desk edition, 4 intergranular fracture in carbon steel in the presence of a caustic material, such as anhydrous ammonia, is typical of stresscorrosion cracking. Corrosion performance of some metals and alloys in liquid. This occurs when contaminants in the ammonia are brought into contact with the steel, a situation that commonly occurs with pressure vessels. Neutron diffraction analysis was used to map the residual stress state in and near circumferential welds from two used anhydrous ammonia nurse tanks, one manufactured in 1966 and the other manufactured in 1986. Reformer tube can also fail by stress corrosion cracking.
During welding, the steel in the heat affected zone haz can get sensitized and this may subsequently lead to stress corrosion cracking. There is some good information available from european fertiliser manufacturers association efma about this. Corrosion and stresscorrosion cracking scc tests were performed on aluminum drillpipe alloy 2014t6 in a waterbased, lowsolids, nondispersed lsnd drilling mud. Stress corrosion cracking scc of the welds in carbon steel transport and storage tanks for anhydrous ammonia has been experienced worldwide for the last 30 years. Neutron diffraction analysis was employed to measure residual stresses near welds in used anhydrous ammonia nurse tanks. Three electrodes commonly used for construction of ammonia storage tanks and one recently developed low strength electrode were studied at ambient temperature. To provide the corrosion engineer with the information to make decisions in individual applications. Ammonia tank research materials science and engineering. Water in ammonia to protect against stress corrosion. Nace publication 5a1922004, integrity of equipment in anhydrous ammonia storage and handling stress corrosion cracking scc of carbon and low alloy steels in anhydrous ammonia service. The vessel can be isolated and taken out of service without any risk of catastrophic failure, but of course the economic consequences for the enduser. Stress corrosion cracking scc is the progressive cracking of metals and alloys caused by the combined effect of sccprone microstructure. This may result in ammonia weeping from a crack within the refrigeration system.
Neutron diffraction analysis was used to map the residual stress state in and near circumferential welds from two used anhydrous ammonia nurse tanks, one manufactured in 1966 and. Carbon and lowalloy steels scc can occur in other materials stainless steel. Anhydrous ammonia explosion in an ice cream plant mcrae. Stress corrosion cracking of carbon steel storage tanks. Anhydrous ammonia is one of the medium where the steel is easy to suffer stress corrosion cracking. Stress corrosion cracking of astm a517 steel in liquid.
Carbon steels in anhydrous ammonia service can suffer from stress corrosion cracking if the water content is less than about 0. Scc requires both exposure to a corrosive environment in this case, ammonia and tensile stress in the steel. This facility originally had a conventional flooded chiller installed. Anhydrous ammonia stress corrosion cracking scc incident. Stress corrosion cracking international institute of. Care must be taken to ensure that pressure vessels are not subjected to this type of corrosion. His letter indicates that the tampa pipeline corporations plan to inhibit stress corrosion cracking in the pipeline amounts to. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. A study of the stress corrosion crack initiation stage in. Astm b858062018, standard test method for ammonia vapor test for determining susceptibility to stress corrosion cracking in copper alloys, astm international, west conshohocken, pa, 2018, back to top. This may result in a catastrophic failure of bulk storage vessels. Citeseerx stress corrosion crack tests of 16mnr low. Stress corrosion cracking of steel in liquefied ammonia. Effect of anhydrous ammonia composition on its ability to.
The analysis showed that tensile residual stresses were present in the tanks measured, and the magnitudes of these stresses approached the. The vessel can be isolated and taken out of service without any risk of catastrophic failure, but of course. This type of damage is a transition form between the classical hydrogen embrittlement and stress corrosion cracking and applies in particular to hightensile steel in low aggressive water solutions, austentitic steel in diluted sulphuric acid, alloys. Predicted growth of throughthickness stress corrosion cracks in. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the. Stress corrosion crack tests of 16mnr low alloy steel in.
The chemical environment that causes scc for a given alloy. Stress corrosion cracking in ammonia did not occur in steel specimens with fatigue precracks, due to a crevice corrosion attack. Typically the indication of a leak due to stress corrosion cracking is a strong smell of ammonia gas seeping through a short hairline crack on a pressure vessel. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented. Stresscorrosion cracking of steels in ammonia with. Stress corrosion cracking of welded carbon steel in liquid ammonia was studied with bend specimens made from carbon steel plates welded with different welding electrodes. The results from four research projects on ammonia stress corrosion cracking scc are provided, including the effect of oxygen and water in the ammonia, prevention of scc with electrochemical methods, crack growth rate studies, and behavior of welds. Department of transportation regulations provide effective safeguards to prevent this problem through the required use of postweld heat treatment and the use of 0. Ammonia at high temperature has high potential for nitriding metals.
In these cases, the cracking was found to be a consequence of inadequate purging of air before introducing the liquid ammonia. The effect of oxygen and water on stress corrosion cracking of mild steel in liquid and vaporous ammonia. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. Stress corrosion cracking is also a possible cause of failures at this weld location. Stress corrosion cracking is caused by the combination of stress in the tanks steel and the corrosive effect of ammonia. Leg weld fatigue cracks in anhydrous ammonia nurse tanks. Corrosionpedia what is stress corrosion cracking scc. Stress corrosion cracking of steel in liquefied ammonia service a. A study was made to determine relevant growth data and to determine methods to prevent cracking. Effect of anhydrous ammonia composition on its ability to cause stress corrosion cracking in steels. Condensed ammonia is a corrodent, and in anhydrous state it can cause stress corrosion cracking of stressed carbon steels or highstrength, lowalloy steels. The possibility of failure of the pressurized vessel adds explosion hazard to the other.
Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. General weight loss corrosion measurements have been conducted on a variety of metals and their alloys that have been used, or have potential use, in liquid ammonia including carbon and low alloy steels, stainless steels, aluminum alloys. Variables examined included chloride concentration, temperature, state of aeration, and effects of galvanic coupling to tooljoint steel. Prevention of stress corrosion cracking of carbon steels. The chemical environment that causes scc for a given alloy is often one which is only mildly corrosive to the metal. Many stress corrosion crack accidents of ammonia storage tanks have been reported all over the world for recent years. This can be avoided with manufacturing procedures that include postweld heat treating and operating practices that include adding water to anhydrous ammonia. The majority of such accidents are caused by stress corrosion cracking of the tank steel.
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